You are here: Home Sections The Department People Faculty Simona Binetti

Simona Binetti

Associate professor

Via Roberto Cozzi, 55
tel.: 02.6448.5177

e-mail: simona.binetti@unimib.it
web page:

Curriculum Vitae

Simona Binetti is associate professor of Physical Chemistry at University of Milano-Bicocca

Born on 03-07-1967. She graduated in Physics at Milano University in 1991, she obtained a Master in Material Science in 1994 with mark 70/70 cum laude and the PH. D. in Chemistry in 1998 and

She is vicedirector of the Milano –Bicocca Solar energy research center MIBSOLAR (www.mibsolar.mater.unimib.it), representing UNIMIB  in  Joint Program on Photovoltaics of European Energy Research Alliance. Qualified Full Professor in Physical Chemistry.

She is responsible of promotion activity of the Science School of University of Milano-Bicocca .


Teaching

Since 2001, she has been teaching:Material Chemistry,Laboratory of Physical Chemistry III,Laboratory of Material Chemistry, Complement of Physical Chemistry, Physical Chemistry of Solid State and Surface and Materials and Devices for Energy.She is  member of the council of the PHD program in Materials Science and Nanotecnology of the University of Milano-Bicocca,. She is responsible of promotion activity of the Science School of University of Milano-Bicocca .

She has been the advisor of  4 PhD students and 7 postdoctoral researchers and of more than 40 master thesis project.

Research

Her research activity has been mainly devoted to the experimental study of the effect of defects (point and extended ones) on electrical and optical properties of elementary semiconductor (Silicon) and composed (Silicon Carbide, Silicon Germanium and alloy and Copper Indium Gallium Diselenied “CIGS” alloy and CZTS alloy). In this context she developed original research activities about the role of defects on the opto-electrical properties of silicon (multicrystalline and nanocrystalline thin film) for photovoltaic application, of optical emission associated to dislocations and oxygen precipitates in silicon, on the epitaxial growth of Er-doped silicon for photonic application. Within this frame, the experimental tools systematically used include UV-IR Photoluminescence systems down to 12 K, infrared and Raman spectroscopy, Hall effect system down to 12 K, the Light Beam Induced Current Technique. She knows all the main characterization methods to analyze the PV device performances, including spectral response/external quantum efficiency measurements and current/voltage characteristics under illumination by solar simulator. Recently in the 2008 a new activity devoted to the growth and characterization of Copper Indium Gallium Diselenied “CIGS” films and CZTS for PV application on steel and glass substrate has been started. The aim of this research is the development of low-cost PV thin films solar cells. In this frame good knowledge has also been developed in thin film deposition methods (e.g. sputtering, evaporation, chemical bath deposition) and in related characterization techniques. Eventually, Simona Binetti is familiar with the most common techniques for the chemical and structural characterization of the materials (e.g: X-ray diffraction, GDMS spectroscopy ,SIMS spectroscopy). Her research group currently includes one assistant professor in Physics, 3 post-doctoral fellow, and 2 PhD students some undergraduated students; the main current scientific interests of the group are materials and devices for inorganic photovoltaics, opto-electronics, and (nano)photonics.

She has published 4 book chapters  and more than 110 papers in peer and editor-reviewed international scientific journals

She did more than 30 oral presentation mainly to PV international conferences and 10 invited talk in the last 5 years.

Main Publications

A. Le Donne , S. Marchionna, M. Acciarri , F. Cernuschi, & S. Binetti “Relevant efficiency enhancement of emerging Cu2MnSnS 4 thin film solar  cells by low temperature annealing  Solar Energy 149  125–131 (2017)

J. Parravicini,  M. Acciarri, A. Lomuscio et al. , and S Binetti “Gallium In-Depth Profile in Bromine- Etched Copper-Indium-Galium-(Di)selenide (CIGS) Thin Films Inspected Using Raman Spectroscopy APPLIED SPECTROSCOPY   Volume: 71   Issue: 6   1334-1339  (2017)

M.I.Khalil, R. Bernasconi, L.Pedrazzetti, A. Lucotti, A. Le Donne, S. Binetti,and L. Magagnin “Co-electrodeposition of metallic precursors for the fabrication of CZTSe thin films solar cells on flexible Mo foil"  Journal of The Electrochemical Society, 164 (6) D302-D306 (2017)

Marchionna, S.; Le Donne, A.; Merlini, M.; et al. Growth of Cu2MnSnS4 PV absorbers by sulfurization of evaporated precursors JOURNAL OF ALLOYS AND COM-POUNDS   Volume: 693   Pages: 95-102   (2017)

Mostafa Boshta, Simona Binetti, Alessia Le Donne, Mohamed Gomaa & Maurizio Acciarri  A chemical deposition process for low-cost CZTS solar cell on flexible substrates, Materials Technology, Vol. 32, - Issue 4 pp 245-249 (2017)

S. Binetti ,  A. Le Donne, A. Rolfi, B. Jäggi, B. Neuenschwander,  C. Busto, C. Frigeri, D. Scorticati,  L. Longoni and S. Pellegrino Picosecond laser texturization of mc-Silicon for photovoltaics: a comparison between 1064 nm, 532 nm and 355 nm radiation wavelengths  Applied Surface Science  371  196–202, (2016)

 

M.I. Khalil, O. Atici , A. Lucotti, S. Binetti , A. Le Donnec, L. Magagnina “CZTS absorber layer for thin film solar cells from electrodeposited metallic stacked precursors (Zn/Cu-Sn)"     Applied Surface Science 379,  91–97 (2016)

A. Scaccabarozzi et al .. “"Integration of InGaP/GaAs/Ge triple-junction solar cells on deeply patterned Silicon substrates"  Prog. Photovolt: Res. Appl   Vol. 24, Issue 10,  1368-1377   (2016)

A. Le Donne, S. Binetti, V. Folegatti , G. Coletti On the nature of striations in n-type silicon solar cells" Applied Physics Letters 109, 033907 (2016);

S. Tombolato, U. Bernerb, D. Colombara, D.Chrastina, M. Widenmeyerc, S.. Binetti  and P.Dale Cu2ZnSnSe4 device obtained by formate chemistry for metallic precursor layer fabrication  Solar Energy 116 (2015) 287–292   (2015)

S. Binetti, M.Gonik , A.LeDonne, A.Croel  Silicon samples grown under reduced melt convection  J. of Crystal Growth 417,  9–15   (2015)

S..Binetti,; P. Garattini, R. Mereu,  A. Le Donne, ; S. Marchionna, A. Gasparotto, M. Meschia, I.  Pinus, M. Acciarri, “Fabricating  Cu(In,Ga)Se2 solar cells on flexible sub-strates by a new roll-to-roll deposition system suitable for industrial applications"   Semicond. Sci . Technol. 30 (2015) 105006

E. Moretti,A. Talon, L. Storaro, A. Le Donne,  S.Binetti, A.Benedetti,  S.Polizzi,Concentration quenching and photostability in Eu(dbm)3phen embedded in mesoporous silica nanoparticles Journal  of luminescence  146  178–185 (2014)

C. Modanese, M. Acciarri, S.Binetti , A.K. Søiland,M.Di Sabatino, L. Arnberg Temperature-dependent Hall-effect measurements of p-type multicrystalline compensated solar grade silicon Prog. Photovolt: Res. Appl 21  1469–1477 (2013)

Le Donne A. , S. K. Jana, S. Banerjee , S. Basu  and S. Binetti “ Optimized luminescence properties of Mn doped ZnS nanoparticles for photovoltaic applications”  Journal of applied Physics J. Appl. Phys. 113, 014903 (2013)

S. Binetti, M.Acciarri, A. Le Donne, M. Morgano, Y Jestin  "Key Success Factors and Future Perspective of Silicon-Based Solar Cells," International Journal of Photoenergy, vol. 2013, Article ID 249502, 6 pages, 2013.

A. Le Donne, A. Scaccabarozzi, S. Tombolato, S. Binetti, M. Acciarri, and A. Abbotto “Solar Photovoltaics: A Review”  Rev. Adv. Sci. Eng. 2, 170-178 (2013)

A. Le Donne, A. Scaccabarozzi, S. Tombolato, S. Marchionna,  P. Garattini, B. Vodopivec, M. Acciarri  and S. Binetti  “State of the Art and Perspectives of Inorganic Photovoltaics” ISRN Renewable Energy, vol. 2013, Article ID 830731, 8 pages, 2013. doi:10.1155/2013/830731.

S. Marchionna, P. Garattini, A. Le Donne, M. Acciarri, S. Tombolato and S. Binetti Cu2ZnSnS4 solar cells grown by sulphurisation of sputtered metal precursors Thin Solid Films 542, 114–118 (2013)

K. S. Jana , A. Le Donne & S. Binetti “Enhancement of silicon solar cell performances due to light trapping by colloidal metal nanoparticles “ Journal of Physics and Chemistry of Solids,  volume 73, issue 2, year 2012, pp. 143 – 147 doi:10.1016/j.jpcs.2011.11.025

A. Le Donne, M. Dilda, M.Crippa, M. Acciarri, S. Binetti,  Optical Materials 33 (2011) 1012–1014  doi:10.1016/j.optmat.2010.10.005

M. Di Sabatino, S. Binetti, J. Libal, M. Acciarri, H. Nordmark, and E.J. Øvrelid, Oxygendis-tribution on a multicrystalline silicon ingot grown from upgraded metallurgical silicon, Solar energy materials and solar cells, Vol.95, 2011, pp.529-533  doi:10.1016/j.solmat.2010.09.013

R.Slunjski, I.Capan, B.Pivac, A.Le Donne, S.Binetti Effects of low-temperature annealing on polycrystalline silicon for solarcells 95 (2011)  559- 563  doi:10.1016/j.solmat.2010.09.016

M.. Morgano,  I. Perez-Wurfl, I & S. Binetti  “Nanostructured Silicon-Based Films for Photo-voltaics: Recent Progresses and Perspectives”  Science of Advanced Materials  Vol.3, pp. 388-400, (2011).

M. Morgano, T. Zhang, I. Perez-Wurfl, s. Binetti, M. Acciarri, & G. Conibeer, Assessment of the composition of Silicon-Rich Oxide films for photovoltaic applications by optical techniques  En-ergy Procedia, Vol. 10, 28-32 (2011) .

M. Acciarri, A. Le Donne, M. Morgano, L. Caccamo, L. Miglio, S. Marchionna, R. Moneta, M. Meschia, & S. Binetti Hybrid sputtering/evaporation deposition of Cu(In,Ga)Se2 thin film solar cells Energy Procedia, Vol. 10,  138-14 (2011)

M. Acciarri, S. Binetti, A. Le Donne, B. Lorenzi, L. Caccamo, L. Miglio, R. Moneta S. Mar-chionna and M. Meschia  Development of a hybrid sputtering/evaporation process for Cu(In,Ga)Se2 thin film solar cells  Cryst. Res. Technol. 46, No. 8, 871 – 876 (2011)

Michio Tajima, Takaaki Iwai, Hiroyuki Toyota, Simona Binetti, and Daniel Macdonald  Donor - acceptor pair luminescence in compensated Si for solar cells JOURNAL OF APPLIED PHYS-ICS 110, 043506 (2011), doi:10.1063/1.3622560

P. L. Novikov, A. Le Donne, S. Cereda, Leo Miglio, S. Pizzini, S. Binetti, M. Rondanini, C. Cavallotti, D. Chrastina, T. Moiseev, H. von Känel, G. Isella, Crystallinity and microstructure in Si films grown by plasma-enhanced chemical vapor deposition: A simple atomic-scale model validated by experiments APPLIED PHYSICS LETTERS 94, 051904 (2009)

A. Le Donne, M. Acciarri, D. Narducci, S. Marchionna and S. Binetti “Encapsulating Eu3+ ComplexDoped Layers to Improve Si-basedSolar Cell Efficiencyc PROGRESS IN PHOTOVOLTAICS: RESEARCH AND APPLICATIONS 17 – 519-525, (2009)

J. Libal, M. Acciarri, S. Novaglio, S. Binetti, R. Petres, J. Arumughan, R. Kopecek, A. Proko-penko “Effect of compensation and of metallic impurities on the electrical properties of Cz-grown solar grade silicon”  J. Appl. Phys. 104, 104507 (2008);

S. M. Hossain A. Anopchenko, S. Prezioso  L. Ferraioli, L. Pavesi, G. Pucker, P. Bellutti, S. Bi-netti, and M. Acciarri  Sub-Band Gap Photo-Response of Nano-Crystalline Silicon in a Metal-Oxide-Semiconductor Device, J. Appl. Phys 104, 0 4917 (2008)

S.Pizzini, S.Binetti, A.Le Donne, A. Marzegalli, A.J. Rabier   “Optical properties of shuffle dislocations in silicon” , Appl. Phys. Lett. 88, 211910 (2006) (USA)

A. Castaldini , D. Cavalcoli, A. Cavallini, S.Pizzini, S.Binetti  “Electronic Transitions at defect states in C p-type silicon” App. Phys. Lett. 86, 162109, (2005)

S.Binetti, M.Acciarri, M.Bollani, L.Fumagalli, H. von Kanel, S. Pizzini Nanocrystalline silicon films grown by Low Energy Plasma Enhanced Chemical Deposition for optoelectronic application Thin Solid Film 487, 19, (2005)

S. Binetti, A. Le Donne, M. Acciarri “Processing step related upgrading of silicon based solar cells detected by photoluminescence spectroscopy” Solar Energy Mat. and Solar Cells  Vol 86/1 pp 11-18 (2005)

S. Binetti, S.Pizzini, E.Leoni, R.Somaschini, A. Castaldini, A. Cavallini, Optical properties of oxygen precipitates and dislocations in silicon J.Appl. Phys. 92, 2437 (2002) (USA)

Projects & Contracts

Currently she is the responsible of :

-European Project FP7 :CHEETACH "Cost-reduction through material optimisation and Higher EnErgy outpuof solAr pHotovoltaic modules - joining Europe’s Research and Development efforts in  support of its PV industry (2013-2017)

-Project of ASI (Agenzia Spaziale Italiana) : N° 101/2012   "Caratterizzazione di silicio multicristallino cresciuto in condizione di microgravità, a partire da silicio metallurgico”

-Project of ESA   European Spatial Agency  ESA 2011-2015 European Spatial Agency (ESA) project N° ESA AO-2009-LoI-0669  "Gravitational effects on heat and mass transport phenomena in directional solidification of upgraded metallurgical silicon for photovoltaic applications” SiSSi (Silicon-ISS Investigation)" (2011-2015) : Unit responsible

- Principal Investigator (P.I) of three  contracts  with  private companies

She has been the responsible of :

  • European Project “FOXY” (“Development of solar grade silicon feedstock for crystalline wafers and cells by purification and crystallisation”) in which she was the local responsible and the leader of the Work package related to Material characterization. (2006-2009)
  • local responsible of a project MISE-CRUI: “Spectrum modification for silicon solar cells” (2008-2011)

    Progetto Lauree scientifiche   Scienza dei Materiali  Unità di Milano-Bicocca  from  2005-2013

  • Since 1990, she has been involved in many European Renewable Energy Projects :

    • Multi-Chess 1990-1993;
    • Multi-Chess II 1993-1996;
    • Cost Effective Solar Silicon Tecnology (COSST) 1996-1999 ;
    • Fast in Line characterization tools for crystalline silicon material and cell process quality control in the PV industry (FAST-IQ) 2000-2003 ;
    • N-type Solar Grade Silicon for Efficient p+n Solar Cells (NESSI) 2002-2005;
    • INTAS (2002-2005)
    • “NANOPHOTO“ (Nanocrystalline silicon films for photovoltaic and optoelectronic applications) Contract Number 013944 (2005-2008),
    • FP7-NMP SME 2012 On the Fly alterable thin film solar modules for design driven applications

    She has been involved in different national projects (Prin2001, Prin 2004, Progetto Fondazione Cariplo “Sviluppo di elettrodi nanostrutturati per la produzione di idrogeno mediante la deposizione fotoelettrochimica dell’ acqua” (2005-2007) ; Progetto fondazione Cariplo “Tecnologie Epitassiali su Silicio per Elettronica e Optoelettronica” (2005­-2008);) Progetto Fondazione Cariplo “Transparent Polymer NANOcomposites with Tailorable Optical Properties: Fabrication and Characterization” (2009-2012); Progetto BANDO MD 2008 DELLA LOMBARDIA: “Celle Solari a Film sottile CuInGaSe2: sviluppo di nuove tecnologie di deposizione e di strutturazione laser” (2008-2010).,

    Memberships

    • Società Chimica Italiana, divisione di chimica fisica, membro del gruppo interdivsionale  ENERCHEM.
    • Consorzio Nazionale Interuniversitario per le Scienze Fisiche della Materia (C.N.I.S.M)
    • L-NESS (Laboratorio per Nanostrutture Epitassiali su Silicio e per Spintronica), centro interuniversitario del Politecnico di Milano e dell'Università di Milano-Bicocca con sede a Como. (member of scientific committe)

    Patents

    Patent N. EP2759619 del 30/07/2014 Plant and process for the production of a semiconductor film

    PCT n.PCT/IB2015/000038 del 16.01.2015 dal titolo: “Novel compounds for the capture of carbon dioxide from gaseous mixtures and subsequent release, related process and plant

    Collaborators

    Alessia Le Donne post doc

    Vanira Trifiletti post doc

    Jacopo Parravicini  post doc