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Alessandro Abbotto

Professore ordinario

Via Roberto Cozzi, 55
tel.: 02.6448.5227
Riceve previo appuntamento.
e-mail:  alessandro.abbotto@unimib.it
web page: http://www.stc.unimib.it/abbotto/

Curriculum Vitae

Education

MS degree in Chemistry from Univ. Milano with honours (1989). Prize for best student in Chemistry of the Univ. Milano (1990). Ph.D. in Chemistry (1993), NSF post-doctoral fellow at UC Berkeley (1994-95), NATO fellow at the Univ. Erlangen-Nuernberg,Erlangen(1995).

Faculty position

Assistant Professor (1995),  Associate Professor (2001), Full Professor (2010) in Organic Chemistry and Materials. University of Milano-Bicocca.

Main Duties

Dean of the undegraduate programs in Chemistry of the University of Milano-Bicocca.

National Coordinator of the Interdivisional Group for Renewable Energy of the Italian Society of Chemistry (EnerCHEM)

Director of the Solar Energy Research Center MIB-SOLAR of the University of Milano-Bicocca

Member of the International Advisory Board of EurJOC (Wiley)

Member of consultants board for MIUR for Programme Horizon 2020, challenge “Energy”

Member of the scientific committee of the Fondazione Tronchetti Provera (Pirelli). Application reviewer for MIUR-Italian Ministry of University and Research, University of Milano, University of Padova, NSF, INSTM-Italian University Consortium on Materials Science and Technology; peer-reviewer for many international scientific journals (ACS, RSC, Wiley, Elsevier).

Research

Co-author of a university textbook in Heterocyclic Chemistry, ca. 125 publications in peer- and editor-reviewed international scientific journals (H index of 25 and ca. 2000 citations) including 18 patents (10 international) and 4 book chapters, and ca. 30 invited talks.

At the present he is the P.I. of a few projects with private companies (eni, Pirelli) and local P.I. of a MIUR-PRIN 2012-14 and of MIUR-Regione Lombardia 2012-14 on organic and hybrid photovoltaics. He has participated in the past 5 years to a number of projects from MIUR-FIRB, MIUR-PRIN, INSTM, CNR, Fondazione Cariplo, EU-FP6 and FP7. Main current scientific interests include materials and devices for organic and hybrid photovoltaics, opto-electronics, and (nano)photonics

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Didattica

ACADEMIC YEAR 2013-14

  • Bachelor Degree Course in Materials Science (first cycle 3-yr degree course): Organic Chemistry (6 ECTS)
  • Bachelor Degree Course in Materials Science (first cycle 3-yr degree course): Organic Chemistry Laboratory (2 ECTS)
  • Master Degree Course in Materials Science (second cycle 2-yr degree course): Materials and Devices for Solar Energy (2 ECTS)
  • Bachelor Degree Course in Chemistry (first cycle 3-yr degree course): Organic Chemistry II (8 ECTS)

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Attività di Ricerca

Current scientific interests involve design, synthesis and characterization of organic and organometallic materials and devices for solar energy, artificila photosynthesis, photonics, and optoelectronics.

Main topics include:

  • organic and organometallic materials for photovoltaic cells (dye-sensitized DSC cells, polymeric-molecular solar cells, tandem DSC-CIGS solar cells)
  • fabrication and characterization of photovoltaic cells and modules
  • artificial photosynthesis: solar induced water splitting, CO2 reduction, solar fuels
  • semiconducting polymers
  • molecular and polymeric optical sensors for water contaminants and explosives

 

He is currently collaborating with many national and international research groups including: University of Milano-Bicocca (R. Ruffo, M. Acciarri, S. Binetti, C. Riccardi, R. Simonutti), University of Milano (R. Ugo, M. Pizzotti, D. Roberto), IIT-Polimi (F. Di Fonzo), University of Padova (C. Ferrante), CNR-Perugia (F. De Angelis), University of Parma (A. Painelli), University of Genova (D. Comoretto), University of Pavia (F. Marabelli), CNR-Bologna (M. Muccini), University of Ferrara (C. Bignozzi), University of Firenze (A. Mordini, P. Foggi), Swiss Federal Institute of Technology-Lausanne (M. K. Nazeeruddin, M. Grätzel).
At the present he is involved as P.I., local P.I. or participant in a number of research projects from national and international government agencies (MIUR-FIRB, MIUR-PRIN, CNR, EU-FP7) and private companies and foundations (Cariplo Foundation, ENI, Pirelli Corimav).

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Principali pubblicazioni

Pubblicazioni recenti (vai a questo link per una lista più completa

Lobello, M. G.; Fantacci, S.; Manfredi, N.; Coluccini, C.; Abbotto, A.; Nazeeruddin, Md. K.; De Angelis, F.
Design of Ru(II) sensitizers endowed by three anchoring units for adsorption mode and light harvesting optimization
Thin Solid Films 2013, ; dx.doi.org/10.1016/j.tsf.2013.08.112.

Collini, E.; Bolzonello, L.; Zerbetto, M.; Ferrante, C.; Manfredi, N.; Abbotto, A.
Lifetime shortening and fast energy transfer processes upon dimerization of a A-π-D-π-A molecule
ChemPhysChem 2013, ; dx.doi.org/10.1002/cphc.201300694.

Calderon, E.; Dangate, M.; Manfredi, N.; Abbotto, A.; Salamone, M.; Ruffo, R.; Mari, C.
Electrochemical and Spectroelectrochemical Properties of a New Donor-Acceptor Polymer Containing 3,4-Dialkoxythiophene and 2,1,3-Benzothiadiazole Units
Polymers 2013, 5, 1068-1080.

Leandri, V.; Ruffo, R.; Trifiletti, V.; Abbotto, A.
Asymmetric Tribranched Dyes: an Intramolecular Co-Sensitization Approach for Dye-Sensitized Solar Cells
Eur. J. Org. Chem. 2013, 6793-6801. (COVER ARTICLE)

Trifiletti, V.; Ruffo, R.; Turrini, C.; Tassetti, D.; Brescia, R.; Di Fonzo, F.; Riccardi, C.; Abbotto, A.
Dye-sensitized solar cells containing plasma jet deposited hierarchical nanostructured TiO2 thin photoanodes
J. Mater. Chem. A 2013, 1, 11665-11673.

Dragonetti, C.; Valore, A.; Colombo, A.; Magni, M.; Mussini, P.; Roberto, D.; Ugo, R.; Valsecchi, A.; Trifiletti, V.; Manfredi, N.; Abbotto, A.
Ruthenium Oxyquinolate Complexes for Dye-Sensitized Solar Cells
Inorganica Chimica Acta 2013, 405, 98-104.

Di Carlo, G.; Orbelli Biroli, A.; Pizzotti, M.; Tessore, F.; Trifiletti, V.; Ruffo, R.; Abbotto, A.; Amat, A.; De Angelis, F.; Mussini, P. R.
Tetraaryl Zn(II) Porphyrinates Substituted at ?-Pyrrolic Positions as Sensitizers in Dye-Sensitized Solar Cells: A Comparison with meso-Disubstituted Push-Pull Zn(II) Porphyrinates“,
Chem. Eur. J. 2013, 19, 10723-10740.

Le Donne, A.; Scaccabarozzi, A.; Tombolato, S.; Binetti, S.; Acciarri, M.; Abbotto, A.
Solar Photovoltaics: A Review
Rev. Adv. Sci. Eng. 2013, 2, 170-178.

Coluccini, C.; Manfredi, N.; Salamone, M. M.; Ruffo, R.; Lobello, M. G.; De Angelis, F.; Abbotto, A.
Quaterpyridine ligands for panchromatic Ru(II) dye sensitizers
J. Org. Chem. 2012; 77, 7945-7956.

Abbotto, A.; Coluccini, C.; Dell’Orto, E.; Manfredi, N.; Trifiletti, V.; Salamone, M. M.; Ruffo, R.; Acciarri, M.; Colombo, A.; Dragonetti, C.; Ordanini, S.; Roberto, D.; Valore, A.
Thiocyanate-free cyclometalated ruthenium sensitizers for solar cells based on heteroaromatic-substituted 2-arylpyridines
Dalton Trans., 2012, 41, 11731-11738.

Dell’Orto, E.; Raimondo, L.; Sassella, A.; Abbotto, A.
Dye-sensitized solar cells: spectroscopic evaluation of dye loading on TiO2
J. Mater. Chem. 2012, 22, 11364 – 11369

Dragonetti, C.; Valore, A.; Colombo, A.; Roberto, D.; Trifiletti, V.; Manfredi, N.; Salamone, M. M.; Ruffo, R.; Abbotto, A.
A new thiocyanate-free cyclometallated ruthenium complex for dye-sensitized solar cells: beneficial effects of substitution on the cyclometallated ligand
J. Organomet. Chem. 2012, 714, 88-93

Abbotto, A.; Seri, M.; Dangate, M. S.; De Angelis, F.; Manfredi, N.; Mosconi, E.; Bolognesi, M.; Ruffo, R., Salamone, M. M.; Muccini, M.
A Vinylene-Linked Benzo[1,2-b:4,5-b']dithiophene-2,1,3-Benzothiadiazole Low-Bandgap Polymer
J. Polym. Sci. Part A 2012, 50, 2829-2840 (COVER ARTICLE)

Abbotto, A.; Leandri, V.; Manfredi, N.; De Angelis, F.; Pastore, M.; Yum, J.-H.; Nazeeruddin, M. K.; Grätzel, M.
Bis-Donor-Bis-Acceptor Tribranched Organic Sensitizers for Dye-Sensitized Solar Cells
Eur. J. Org. Chem., 2011, 6195

Coluccini, C.; Manfredi, N.; Herrera Calderon, E.; Salamone, M. M.; Ruffo, R.; Roberto, D.; Lobello, M. G.; De Angelis, F.; Abbotto, A.
Photophysical and Electrochemical Properties of Thiophene-Based 2-Arylpyridines
Eur. J. Org. Chem., 2011, 5587-5595

Abbotto, A.; Manfredi N.
Electron-rich heteroaromatic conjugated polypyridine ruthenium sensitizers for dye-sensitized solar cells (review)
Dalton Trans., 2011, dx.doi.org/10.1039/C1DT10832H (COVER ARTICLE)

Mosquera Vázquez, S.; Abbotto, A.; De Angelis, F.; Foggi, P.; Lapini, A.; Lima, M.; Lobello, M.; Marcelli, A.; Tourón Touceda, P.
Transient absorption spectroscopy of a heteroaromatic donor-acceptor-pi-conjugated 2,2′-bipyridine dye
J. Mol. Struct. 2011, 993, 464-469.

Abbotto, A.; Herrera Calderon, E.; Manfredi, N.; Mari, C. M.; Marinzi, C.; Ruffo, R.
Vinylene-Linked Pyridine-Pyrrole Donor-Acceptor Conjugated Polymers
Synth. Metals 2011, 161, 763-769.

Abbotto, A.; Sauvage, F.; Barolo, C.; De Angelis, F.; Fantacci, S.; Graetzel, M.; Manfredi, N.; Marinzi, C.; Nazeeruddin, M. K.
Panchromatic ruthenium sensitizer based on electron-rich heteroarylvinylene p-conjugated quaterpyridine for dye-sensitized solar cells
Dalton Trans. 2011, 40, 234-242.

Abbotto, A.; Herrera Calderon, E.; Dangate, M. S.; De Angelis, F.; Manfredi, N.; Mari, C. M.; Marinzi, C.; Mosconi, E.; Muccini, M.; Ruffo, R.; Seri, M.
Pyridine-EDOT Heteroarylene-Vinylene Donor-Acceptor Polymers
Macromolecules 2010, 43, 9698-9713.

Progetti e contratti

Progetti recenti (aggiornamento Novembre 2013)

  • 2013-2015: MIUR – PRIN 2010 (local P.I.)
    DSSC X – Next Generation Dye Solar Devices: Nanoengineered Conductors and Sensitizers
  • 2012-2014: MIUR – Regione Lombardia (local P.I.)
    TIFAIN – Tessere integrate di vetro fotovoltaico per applicazioni architettoniche innovative.
  • 2010-2013: Research Contract (P.I.)
    DSC organic phosensitizers.
  • 2010-2012: MIUR – PRIN 2008 (local P.I.)
    Design and development of new components for highly efficient dye-sensitized solar cells.
  • 2010-2012: FONDAZIONE CARIPLO (local P.I.)
    Photonic enhancement in chemical sensors: nanomaterials for optics (PHOENICS).
  • 2009-2011: FONDAZIONE CARIPLO (local P.I.)
    Progettazione e utilizzo di nuovi materiali organometallici o di coordinazione per celle solari organiche di terza generazione.
  • 2008-2011: FONDAZIONE CARIPLO (P.I.)
    Modulazione delle proprietà elettroniche e optoelettroniche di nuovi semiconduttori polimerici: progettazione da unità donatrici-accettrici, sintesi e caratterizzazione.

Brevetti

Brevetti recenti (vai a questo link per un elenco completo)

Abbotto, A.; Simonutti, R.; Manfredi, N.; Bianchi, A.
“Block copolymer-based solid electrolytes for dye photovoltaic cells, and cells thus obtained”
PCT Int. Appl. 2012, WO 2012/153300.

Maiorana, S.; Licandro, E.; Longhi, E.; Cauteruccio, S.; Abbotto, A.; Baldoli, C.; De Angelis, F.
“Metal-free photosensitizers”
PCT Int. Appl. 2012; WO 2012/107488.

Abbotto, A.; Comoretto, D.; Gagliardi, F.; Marabelli, F.
“Nuovi composti otticamente sensibili ai composti elettron-poveri”,
Ital. Patent. Appl. 2012, MI2012A000636

Abbotto, A.; Manfredi, N.; Comoretto, D.; Gagliardi, F.; Marabelli, F.
“Nuovi polimeri otticamente sensibili ai composti elettron-poveri”,
Ital. Patent. Appl. 2012, MI2012A000637

Abbotto, A.; Manfredi, N.; Coluccini, C.; Roberto, D.; Ugo, R.; Dragonetti, C.; Valore, A.; Colombo, A.
“New Cyclometalated Complexes for Solar Cells”
PCT Int. Appl. 2012, WO 2012013719 A1 20120202.

Abbotto, A.; Simonutti, R.; Manfredi, N.; Bianchi, A.
“Celle fotovoltaiche a colorante con elettroliti solidi a base di copolimeri a blocchi”
italian patent application, 2011

Abbotto, A.; De Angelis, F.; Nazeeruddin, M. D.; Graetzel, M.; Marinzi, C.; Manfredi, N.
Novel Ligands for Sensitizing Dyes of Dye-Sensitized Solar Cells
PCT Int. Appl. (2011), WO 2011039715 A1 20110407, 2009, date of publication: 7 April 2011.

Abbotto, A.; Manfredi, N.; Coluccini, C.; Roberto, D.; Ugo, R.; Dragonetti, C.; Valore, A.; Colombo, A.
“Nuovi complessi ciclometallati per celle solari”
italian patent application, 2010

Collaboratori

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